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Selected Publications

Fuel Cell Reviews and Commentaries

• S. M. Haile, Nature Journal Club - Commentary on advanced anodes for solid oxide fuel cells, Nature 443, 375 (2006).

• S. M. Haile, "Fuel Cell Materials and Components," Acta. Met. 51, 5981-6000 (2003).

• S. M. Haile, "Materials for Fuel Cells," Materials Today 18, 24-29 (2003).

Fuel Cells, Electrocatalysis and Catalysis

• K. Sasaki, Y. Hao and S. M. Haile, “Geometrically asymmetric electrodes for probing electrochemical reaction kinetics: A case study of hydrogen at the Pt-CsH2PO4 interface,” Phys. Chem. Chem. Phys.

• G. A. Umeda, W. C. Chueh, L. Noailles, S. M. Haile and B. S. Dunn “Inverse Opal Ceria-Zirconia: Architectural Engineering for Heterogeneous Catalysis,” Eng. Env. Sci. (invited, advance article) 1, 484-486 (2008). DOI: 10.1039/b810641j

• W. C. Chueh, W. Lai and S. M. Haile, “Electrochemical Behavior of Ceria with Selected Metal Electrodes,” Solid State Ionics, 179, 1036-1041 (2008). DOI: 10.1016/j.ssi.2007.12.087.

• W. C. Chueh, Z. Shao and S. M. Haile, “Tunability of propane conversion over alumina supported Pt and Rh,” Topics in Catalysis (invited) 46, 402-413 (2007).

• S. M. Haile, C. R. I. Chisholm, K. Sasaki, D. A. Boysen and T. Uda, “Solid acid proton conductors: From laboratory curiosities to fuel cell electrolytes,” Faraday Discussions (cover image) 134, 17-39 (2007).

• T. Uda, D. A. Boysen, C. R. I. Chisholm and S. M. Haile, “Alcohol Fuel Cells at Optimal Temperatures,” Electrochem. Solid State Lett. 9, A261-A264 (2006).

• Z. Shao, J. Mederos, W. C. Chueh and S. M. Haile, “High Power Density Single Chamber Fuel Cells Operated on Methane,” J. Power Sources 168, 589-596 (2006).

• Y. Hao, Z. Shao, J. Mederos, W. Lai, D. G. Goodwin and S. M. Haile, “Recent Advances in Single-Chamber Fuel-Cells: Experiment and Modeling,” Solid State Ionics 177, 2013-2021 (2006).

• Z. P. Shao, S. M. Haile, J. M. Ahn, P.D. Ronney, Z. L. Zhan and S. A. Barnett, "A thermally self-sustained micro Solid-Oxide Fuel Cell stack with high power density," Nature 435, 795-798 (2005).

• T. Uda and S. M. Haile, "Thin-Membrane Solid-Acid Fuel Cell," Electrochem. Solid State Lett. 8, A245-A246 (2005).

• Z. Shao and S. M. Haile, "A High Performance Cathode for the Next Generation Solid-Oxide Fuel Cells," Nature 431, 170-173 (2004).

• D. A. Boysen, T. Uda, C. R.I. Chisholm and S. M. Haile, "High performance Solid Acid Fuel Cells through humidity stabilization," Science Online Express, Nov 20, 2003; Science 303, 68-70 (2004).

• Z. Shao, C. Kwak, S. M. Haile, "Preparation and investigation of anode-supported thin-film fuel cells operated in a single chamber configuration," Solid State Ionics 175, 39-46 (2004).

• S. M. Haile, D. A. Boysen, C. R. I. Chisholm and R. B. Merle, "Solid Acids as Fuel Cell Electrolytes," Nature 410, 910-913 (2001).

• D. A. Boysen, C. R. I. Chisholm, S. M. Haile and S. R. Narayanan, "Polymer Solid Acid Composite Membranes for Fuel Cell Applications," J. Electrochem. Soc. 147, 3610-3614 (2000).
  

Oxide Ion and Mixed Conductors (Fundamentals)

• W. Lai and S. M. Haile, “Electrochemical impedance spectroscopy of mixed conductors under a chemical potential gradient: A case study of Pt|SDC|BSCF,” Phys. Chem. Chem. Phys. (advance article) 10, 865-883 (2008).

• W. Lai and S. M. Haile, "Impedance Spectroscopy as a Tool for Chemical and Electrochemical Analysis of Mixed Conductors: A Case Study of Ceria," J. Amer. Cer. Soc. 88, 2979-2997 (2005). [Invited feature article]

Proton Conducting Perovskites

• Yoshihiro Yamazaki, Raul Hernandez-Sanchez and Sossina M. Haile, “High total proton conductivity in Y-doped BaZrO3,” Chem. Mater

• Y. Yamazaki, P. Babilo and S. M. Haile, “Defect chemistry of yttrium-doped BaZrO3 – A thermodynamic analysis of defect incorporation,” Chem. Mater. 20, 6352-6357 (2008).

• P. Babilo, T. Uda and S. M. Haile, “Processing of Yttrium Doped Barium Zirconate for High Proton Conductivity,” J. Mat. Res. 22, 1322-1330 (2007).

• C. Y. Jones, J. Wu, L.P. Li and S. M. Haile, "Hydrogen Content in Doped and Undoped BaPrO₃ and BaCeO₃ by Cold Neutron Prompt-Gamma Activation Analysis," J. Appl. Phy. 97, 114908-1-4. (2005)

• J. Wu, R. A. Davies, M. S. Islam, and S. M. Haile, "Atomistic Study of Doped BaCeO₃: Dopant Site-Selectivity and Cation Non-stoichiometry," Chem. Mat. 17, 846-851 (2005).

• T. A. Mary, C. Y. Jones, G. J. Snyder and S. M. Haile, "Nonstoichiometry, Structure and Electrical Properties of 'SrPrO₃'," Chem. Mat. 17, 5146-5154 (2005).

• P. Babilo and S. M. Haile, "Enhanced Sintering of Yttrium doped Barium Zirconate by Addition of ZnO," J. Amer. Cer. Soc. 88, 2362-2368 (2005).

• J. Wu, S. M. Webb, S. Brennan and S. M. Haile, "Dopant Site Selectivity in BaCe0.85M0.15O3-d by Extended X-ray Absorption Fine Structure," J. Appl. Phys. 97, 054101 (2005).

• J. Wu, L. P. Li, W. T. P. Espinosa, and S. M. Haile, "Defect Chemistry and Transport Properties of Ba_xCe_0.85M_0.15O_3-d," J. Mat. Res. 19, 2366-2376 (2004).

• S. M. Haile, D. L. West and J. Campbell "The Role of Microstructure and Processing on the Proton Conducting Properties of Gadolinium-Doped Barium Cerate," J. Mat. Res. 13, 1576-1595 (1998).

• D. Shima and S. M. Haile "The Influence of Cation Non-Stoichiometry on the Properties of Undoped and Gadolinia-Doped Barium Cerate," Solid State Ionics 97, 443-447 (1997).

Solid Acid Compounds

• L. A. Cowan, R. M. Morco, N. Hatada, A. Navrotsky and S. M. Haile, “High temperature properties of Rb₃H(SO₄)₂ at ambient pressure: Absence of a superprotonic transition,” Solid State Ionics, 179, 305-313 (2008).

• Y. K. Taninouchi, T. Uda, Y. Awakura, A. Ikeda and S. M. Haile, “Dehydration Behavior of the Superprotonic Conductor CsH₂PO₄ at Moderate Temperatures: 230 to 260°C,” J. Mater. Chem. 17, 3182-3189 (2007). (Invited)

• C. R. I. Chisholm and S. M. Haile, “Entropy Evaluation of the Superprotonic Phase of CsHSO₄: Pauling’s Ice Rules Adjusted for Systems Containing Disordered Hydrogen-Bonded Tetrahedra,” Chem. Mat. 19, 270-279 (2007).

• C. R. I. Chisholm, Y. H. Jang, S. M. Haile and W. A. Goddard, III, "The Superprotonic Phase Transition of CsHSO₄: A Molecular Dynamics Simulation Study," Phys. Rev. B. 72, 134103 (2005).

• T. Uda, D. A. Boysen and S. M. Haile, "Thermodynamic Analysis and Electrochemical Evaluation of CsHSO₄," Solid State Ionics 176, 127-133 (2005).

• D. A. Boysen, S. M. Haile, H. Liu and R. A. Secco, "Conductivity of Potassium and Rubidium Dihydrogen Phosphates at High Temperature and Pressure," Chem Mat. 16, 693-397 (2004).

• W. T. Klooster, R. O. Piltz, T. Uda and S. M. Haile, "Structure Refinement and Chemical Analysis of Cs₃Li(DSO₄)₄, formerly 'Cs_1.5Li_1.5D(SO₄)₂'," J. Solid State Chem. 177, 274-280 (2004).

• D. A. Boysen, S. M. Haile, H. Lui and R. A. Secco "High-temperature Behavior of CsH₂PO₄ under both Ambient and High Pressure Conditions," Chem. Mat. 15, 727-736 (2003).

• C. R. I. Chisholm, R. B. Merle, D. A. Boysen and S. M. Haile, "Superprotonic Phase Transition in CsH(PO₃H)," Chem. Mat. 14, 3889-3893 (2002).

• C. R. I. Chisholm, L. A. Cowan and S. M. Haile, "Synthesis, Structure and Properties of Compounds in the NaHSO₄-CsHSO₄ system II: The Absence of Superprotonic Transitions in Cs₂Na(HSO₄)₃and CsNa₂(HSO₄)₃," Chem. Mat. 13, 2909-2912 (2001).

• C. R. I. Chisholm, L. A. Cowan, S. M. Haile and W. T. Klooster, "Synthesis, Structure and Properties of Compounds in the NaHSO₄-CsHSO₄ system I: Crystal structures of Cs₂Na(HSO₄)₃and CsNa₂(HSO₄)₃," Chem. Mat. 13, 2574-2583 (2001).

• C. R. I. Chisholm and S. M. Haile, "X-ray Structure Refinement of CsHSO₄ in Phase II," Mat. Res. Bull. 35, 999-1005 (2000).

• C. R. I. Chisholm and S. M. Haile, "Superprotonic Behavior Cs₂(HSO₄)(H₂PO₄) - A New Solid Acid in the CsHSO₄ - CsH₂PO₄ System," Solid State Ionics 136-137, 229-241 (2000).

• C. R. I. Chisholm and S. M. Haile, "Structure and Thermal Behavior of the New Superprotonic Conductor Cs₂(HSO₄)(H₂PO₄)," Acta Cryst. B55, 937-946 (1999). Note also the erratum, published to correct a printing error.

• S. M. Haile and W. T. Klooster, "Single-Crystal Neutron Diffraction Study of
  b-Cs₃(HSO₄)₂(H_2-x(P_1-x,S_x)O₄) (x ~ 0.5) at 15K," Acta Cryst. B55, 285-296 (1999).
  

• S.M. Haile, P. Calkins and D. Boysen, "The structure and vibrational spectrum of b-Cs₃(HSO₄)₂(H_2-x(P_1-x,S_x)O₄) (x ~ 0.5), a new superprotonic conductor, and a comparison with a-Cs₃(HSO₄)₂(H₂PO₄)," J. Solid State Chem. 139, 373-387 (1998).

• S.M. Haile and P. Calkins, "X-ray diffraction study of Cs₅(HSO₄)₃(H₂PO₄)₂, a New Solid Acid with a Unique Hydrogen-Bond Network," J. Solid State Chem. 140, 251-265 (1998).

• S.M. Haile, P. Calkins and D. Boysen, "Superprotonic Conductivity in
  b-Cs₃(HSO₄)₂(H_x(P,S)O₄)," Solid State Ionics 97, (1997) 145-151.

• S.M. Haile, K.-D. Kreuer and J. Maier, "The Structure of Cs₃(HSO₄)₂(H₂PO₄) -- a New Compound with a Superprotonic Transition," Acta Cryst. B51, (1995) 680-687.

• S.M. Haile, G. Lentz, K.-D. Kreuer and J. Maier, "Superprotonic Conductivity in Cs₃(HSO₄)₂(H₂PO₄)," Solid State Ionics 77, (1995) 128-134.

Thin Film Ferroelectric Perovskites

• R. T. Brewer, D. A. Boyd, M. Y. El-Naggar, S. W. Boland, Y.-B. Park, S. M. Haile, D. G. Goodwin, and H. A. Atwater, "Growth of biaxially textured Ba_xPb_1-xTiO₃ ferroelectric thin films on amorphous Si₃N₄," J. Appl. Phys. 97, 034104 (2004).

• S. W. Boland, S. C. Pillai, and S. M. Haile, "Low Temperature Crystallization of Sol-Gel Processed Pb_0.5Ba_0.5TiO₃," J. Amer. Cer. Soc. 87, 1388-1391 (2004).

• S. W. Boland, S. C. Pillai, W.-D. Yang and S. M. Haile, "Preparation of (Pb,Ba)TiO₃ Powders and Highly-Oriented Thin Films by a Sol-Gel Proces," J. Mat. Res. 19, 1492-1498 (2004).

Thermoelectrics

• E. S. Toberer, K. A. Sasaki, C. R. I. Chisholm, S. M. Haile and G. J. Snyder, “Local structure of interstitial Zn in b-Zn₄Sb₃,” phys. stat. sol. (RRL) 1, 253–255 (2007).

• T. Ikeda, V. A.Ravi, L. A. Collins, S. M. Haile and G. J. Snyder, “Development and Evolution of Nanostructure in Bulk Thermoelectric Pb-Te-Sb Alloys,” J. Elect. Mat. 37, 716-720 (2007).

• H. J. Kim, E. S. Božin, S. M. Haile, G. J. Snyder and S. J. L. Billinge, “Nano-scale alpha-structural domains in the phonon-glass thermoelectric material beta-Zn₄Sb₃,” Phys. Rev. B. 75, accepted (2007).

• T. Ikeda, L. A. Collins, V. Ravi, F. S. Gascoin, S. M. Haile and G. J. Snyder, “Self-Assembled Nanometer Lamellae of Thermoelectric PbTe and Sb₂Te₃ with Epitaxy-like Interfaces,” Chem. Mat. 19, 763-767 (2007).

• T. Ikeda, S. M. Haile, H. Azizgolshani, F. Gascoin, V. A. Ravi and G. J. Snyder, “Solidification microstructure of alloys in the pseudo-binary PbTe-Sb₂Te₃ system,” Acta Met. 55, 1227-1239 (2007)

• .F. Gascoin, S. Ottensmann, D. Stark, S. M. Haile, G. J. Snyder, "Zintl Phases as Thermoelectric Materials: Tuned Transport Properties of the Compounds
  Ca_xYb_1-xZn₂Sb₂," Adv. Funct. Mat. 15, 1860-4 (2005)

Alkali Ion Conducting Silicates

• S. M. Haile and B. J. Wuensch, "X-ray Diffraction Study of K₃NdSi₇O₁₇- a New Framework Silicate with a Linear Si-O-Si bond," Acta Cryst. B56, 773-779 (2000).

• S. M. Haile, B. J. Wuensch and T. Siegrist, "Structure and Conductivity of K₈Nd₃Si₁₂O₃₂(OH)," J. Sol. State Chem. 148, 406-418 (1999).

• S.M. Haile and B.J. Wuensch, "Comparison of the crystal-chemistry of selected (MSi₆O₁₅)-based silicates." Amer. Min., 82, (1997) 1141-1149.

• S.M. Haile, B.J. Wuensch, R.A. Laudise and J. Maier, "The Structure of Na₃NdSi₆O₁₅•2H₂O -- A Layered Silicate with Paths for Possible Fast Ion Conductor." Acta Cryst. B53 (1997) 7-17.

• S.M. Haile, B.J. Wuensch, R.A. Laudise and J. Maier, "The Structure of Na₃YSi₆O₁₅ -- A Unique Silicate Based on Discrete Si₆O₁₅ Units and a Possible Fast Ion Conductor." Acta Cryst B51 (1995) 673-680.

• S.M. Haile, B.J. Wuensch and R.A. Laudise, "Hydrothermal Synthesis of New Alkali Silicates I. Potassium Neodymium Phases & II. Sodium Neodymium and Sodium Yttrium Phases." J. Cryst. Growth 131 (1993) 352-372 & 373-386.

• S.M. Haile, B.J. Wuensch, T. Siegrist and R.A. Laudise, "Conductivity and Crystallography of New Alkali-Rare Earth Silicates Synthesized as Possible Fast Ion Conductors." Solid State Ionics 53-56 (1992) 1292-1301.

 

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Last modified: September 14, 2009