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Teaching Program
Caltech Courses, 2011-2012
Topics:
Crystalline and amorphous structure, defects in crystals, thermodynamics,
phase diagrams, properties of materials: mechanical, electrical, optical
and magnetic.
- MS/EST
143 - Solid State Electrochemistry for Energy Storage and Conversion - Spring 2013
Topics: Thermodynamics and kinetics of ion and electron transport in solids, with emphasis on processes in electrolyte and electrode materials used in energy storage and conversion. Treatment of electroanalytical characterization techniques including a.c. impedance spectroscopy, voltametry, and d.c. polarization methods. Application areas include fuel cells, electrochemical gas separation membranes, batteries, supercapacitors, and hydrogen storage materials.
Although no prerequisites are listed in the course catalog for MS 143, students with no prior exposure to materials science and engineering will be at a disadvantage. MS 115a is suggested.
Recently Offered Courses
Topics:
Crystalline and amorphous structure, defects in crystals, thermodynamics,
phase diagrams, properties of materials: mechanical, electrical, optical
and magnetic.
Topics:
Experimental methods, quantitative phase analysis, crystallite size
measurement, lattice parameter refinement, internal stress measurement,
quantification of preferred orientation (texture) in materials, Rietveld
refinement, and determination of structural features from small angle
scattering
Topics: Thermodynamics and kinetics of ion and electron transport in solids, with emphasis on processes in electrolyte and electrode materials used in energy storage and conversion. Treatment of electroanalytical characterization techniques including a.c. impedance spectroscopy, voltametry, and d.c. polarization methods. Application areas include fuel cells, electrochemical gas separation membranes, batteries, supercapacitors, and hydrogen storage materials.
Although no prerequisites are listed in the course catalog for MS 143, students with no prior exposure to materials science and engineering will be at a disadvantage. MS 115a is suggested.
Lectures may be recorded and made available for on-line viewing. Lectures from 2011 and 2009 are available for worldwide access, through the links above.
Topics: State-of-the-art in the use of concentrated solar energy to drive electrical power plants and general fuel. Topics covered include: (1) Fundamentals of solar concentration: optics, trough/tower/dish systems, non-imaging systems (compound parabolic concentrator). (2) Solar thermal electricity generation: Rankine/Brayton/Stirling-based cycles, receiver technology, hybridization, thermal storage, energy economics. (3) Solar thermochemical fuel production: thermodynamics, processes (H2O/CO2-splitting, thermochemical cycles, decarbonization), reactor technology, life cycle analysis.
Instructor: A. Steinfeld.
Topics:
Phase transformations in solids
Topics:
Overview of quantum mechanics of atoms, molecules and solids, molecular
orbitals, chemical bonding, band structures, point defects, line defects
(dislocations).
Tutorial Information
- Fuel
Cells - In recent years, many review articles, monographs and textbooks on fuel cell have appeared. The items below are just some samples.
Here's
a tutorial put together by Los Alamos National Laboratory, emphasizing
Polymer Electrolyte Membrane (PEM) fuel
cells for automotive applications (in pdf format). You may
also be interested in a pamphlet put together by the National Energy
Techology Lab, emphasizing market and technology aspects of higher
temperature fuel cells.
Here's
a "popular press" article on our solid
acid fuel cells which appeared in the Caltech publication
ENGenious.
- A.C.
Impedance Spectroscopy - Highly recommended is the 2008 textbook by Orazem and Tribollet, "Electrochemical Impedance Spectroscopy" published by Wiley as an ECS monograph.
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